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2002 Wilton Cake adorning Yearbook. 100 of recent adorning rules.

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Substrates, thereby indicating their high potential for high-resolution imaging and fast kinetic measurement. 2 Nanopipette-Supported ITIES Tips A nanometer-scale ITIES can be supported by a nanopipette to serve as a versatile SECM tip to probe both electron-transfer and ion-transfer reactions [120]. Nanoscale Scanning Electrochemical Microscopy 35 A nanopipette can be filled with the solution of a redox active species to drive the electron-transfer reaction of a species in the outer solution [102].

9c). 9 (a) Constant-current and (b) constant-height images of a human breast epithelial (MCF-10A) cell obtained with 123- and 47-nm-radius Pt nanotips, respectively. (c) Approach and penetration of an MCF-10A cell by a 144-nm-radius Pt tip. The inset shows the experimental (symbols) and theoretic (solid line) curves for the final part of the approach curve, where the tip approached the bottom of the petri dish. The extracellular PBS solution contained 1 mM Ru(NH3)6Cl3 in (a) and 1 mM FcCH2OH in (b) and (c).

Chem. , Vol. 133, 2011: pp. 15737–15742. 1 M tetrabutylammonium hexafluorophosphate as obtained with a 5-μm-radius Pt tip with a thin-glass sheath. 45–2 μm between the tip and the substrate are indicated. 6 μm. 005 V/s in panels C and D, respectively. (Reprinted with permission from Shen, M. , Achieving nanometer scale tip-to-substrate gaps with micrometer-size ultramicroelectrodes in scanning electrochemical microscopy, Anal. , Vol. 83, 2011: pp. 9082–9085. 1 cm/s. In contrast, the reduction of the bipyridine ligand was too fast to observe a kinetic effect on a nanogap-based tip voltammogram.

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